03488nam a22004695i 4500 978-0-387-28690-7 DE-He213 20260521091849.0 cr nn 008mamaa 100301s2005 xxu| s |||| 0|eng d 9780387286907 99780387286907 10.1007/0-387-28690-X doi CICY 541.395 23 Vannice, M. Albert. author. Solutions Manual for Kinetics of Catalytic Reactions [recurso electrónico] / by M. Albert Vannice. Boston, MA : Springer US, 2005. 98 p. online resource. text txt rdacontent computer c rdamedia recurso en línea cr rdacarrier text file PDF rda Catalyst Characterization -- Acquisition and Evaluation of Reaction Rate Data -- Adsorption and Desorption Process -- Kinetic Data Analysis and Evaluation of Model Parameters for Uniform (Ideal) Surfaces -- Modeling Reactions on Uniform (Ideal) Surfaces -- Modeling Reaction on Nonuniform (Nonideal) Surfaces -- Kinetics of Enzyme-Catalyzed Reactions. This textbook contains all the information needed for graduate students or industrial researchers to design kinetic experiments involving heterogeneous catalysts, to characterize these catalysts, to acquire valid rate data, to verify the absence of mass (and heat) transfer limitations, to propose reaction models, to derive rate expressions based on these models and, finally, to assess the consistency of these rate equations. Langmuir, Freundlich, and Temkin isotherms are derived and the former are used in Langmuir-Hinshelwood (and Hougen-Watson) models, as well as reaction sequences without a rate-determining step, to obtain rate expressions on uniform surfaces. In addition, rate equations based on non-uniform (Temkin-type) surfaces are examined as an alternative approach. The most recent technique to calculate heats of adsorption and activation barriers on metal surfaces, the BOC-MP approach, is discussed in detail. Methods to measure metal surface areas and crystallite sizes using x-ray diffraction, transmission electron microscopy and various chemisorption techniques are discussed. Different experimental techniques to determine the influence of mass transfer limitations, especially within the pores of a catalyst, are reviewed in detail, with a particular emphasis on liquid-phase reactions. Many illustrations of these and other topics are provided along with numerous problems and a Solutions Manual for instructors. This book will be applicable to any graduate course in chemical engineering, chemistry or materials science that involves kinetics of catalytic reactions, including those catalyzed by enzymes. CHEMISTRY. CHEMISTRY, INORGANIC. CHEMISTRY, PHYSICAL ORGANIC. CHEMICAL ENGINEERING. CATALYSIS. CHEMISTRY. CATALYSIS. INDUSTRIAL CHEMISTRY/CHEMICAL ENGINEERING. INORGANIC CHEMISTRY. PHYSICAL CHEMISTRY. SpringerLink (Online service) Springer eBooks Printed edition: 9780387259734 http://dx.doi.org/10.1007/0-387-28690-X Ver el texto completo en las instalaciones del CICY ddc ER 32790 32790 0 0 ddc 0 0 LE CICY CICY EL 2025-07-10 0 541.395 2025-07-10 08:39:42 2025-07-10 ER