01955nam a2200277Ia 4500 MX-MdCICY 20260521091738.0 CICY B-20606 Unraveling the Asymmetric O- O Radical Coupling Mechanism on Ru- O- Co for Enhanced Acidic Water Oxidation Small, 19(45), p.2304889, 2023 Heterogeneous oxides with multiple interfaces provide significant advantages in electrocatalytic activity and stability. However, controlling the local structure of these oxides is challenging. In this work, unique heterojunctions are demonstrated based on two oxide types, which are formed via pyrolysis of a ruthenocene metal-organic framework (Ru-MOF)at specific temperatures. The resulted Ru-MOF-400 exhibits excellent electrocatalytic activity, with an overpotential of 190 mV at a current density of 10 mA cm-2 in 0.1 m HClO4 , and a mass activity of 2557 A gRu -1 , three orders of magnitude higher than commercial RuO2 . The Ru?O?Co bond formed by the incorporation of Co into the rutile lattice of RuO2 inhibits the disolution of Ru. Operando electrochemical investigations and density functional theory results reveal that the Ru-MOF-400 undergo asymmetric dual-active site oxide path mechanism during the acidic oxygen evolution reaction process, which is predominantly mediated by the asymmetric Ru?Co dual active site present at the interfaces between Co3 O4 and CoRuOx ACIDIC OXYGEN EVOLUTION REACTION ELECTROCATALYSTS HETEROGENEOUS OXIDES Liang, J. Gao, X. Xu, K. Lu, J. Liu, D. Zhao, Z. Liu, J. https://drive.google.com/file/d/17vka6kazEmnsG2zx72qrmftocHxsfg8A/view?usp=drivesdk Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx Loc REF1 250602s9999 xx |||||s2 |||| ||und|d 30631 30631 0 0 Loc 0 0 F1 CICY CICY RE 2025-06-25 0 B-20606 2025-06-25 16:24:52 2025-06-25 REF1