02060nam a2200313Ia 4500003001000000005001700010040000900027090001200036245019800048490005200246520090900298650001301207650002501220650001301245650002101258650002001279650002201299650001401321700001901335700001101354700001701365700001501382700001801397856015601415942001401571008004101585999001701626952010301643MX-MdCICY20260521091309.0  cCICY  aB-1220210aInterface/interphase engineering of polymers for adhesion enhancement: Part II. Theoretical and technological aspects of surface-engineered interphase-interface systems for adhesion enhancement0 vThe Journal of Adhesion, 79(5), p.483-519, 20033 aPart I of this paper reviewed the theoretical principles of the macromolecular design of polymer interface=interphase systems for obtaining maximum adhesion and fracture performance of adhesively bonded assemblies. In Part II a novel, relatively simple and industry-feasible technology for surface-grafting connector molecules is demonstrated and discussed in detail and supported by a range of experimental examples. It is shown, in agreement with contemporary theory, that the use of chemically attached graft chemicals of controlled spatial geometry and chemical functionality enables a significant increase in the strength and fracture energy of the interphase, to the point of cohesive fracture of the substrate, or that of an adjacent medium such as adhesive, elastomer, or other material. This occurs even after prolonged exposure of investigated systems to adverse environments such as hot water.14aPOLYMERS14aSURFACE MODIFICATION14aADHESION14aADHESIVE BONDING14aFRACTURE ENERGY14aMOLECULAR BRUSHES14aADHESIVES12aGutowski, W.S.12aLi, S.12aFilippou, C.12aHoobin, P.12aPetinakis, S.40uhttps://drive.google.com/file/d/1BducDTp5jazuGTp59rRuhSHQNGMKVLeD/view?usp=drivesdkzPara ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx  2LoccREF1250602s9999    xx |||||s2   |||| ||und|d  c22352d22352  00102Loc40708F1aCICYbCICYcREd2025-06-25l0oB-12202r2025-06-25 14:07:05w2025-06-25yREF1