01945nam a2200301Ia 4500 MX-MdCICY 20260521091309.0 CICY B-12202 Interface/interphase engineering of polymers for adhesion enhancement: Part II. Theoretical and technological aspects of surface-engineered interphase-interface systems for adhesion enhancement The Journal of Adhesion, 79(5), p.483-519, 2003 Part I of this paper reviewed the theoretical principles of the macromolecular design of polymer interface=interphase systems for obtaining maximum adhesion and fracture performance of adhesively bonded assemblies. In Part II a novel, relatively simple and industry-feasible technology for surface-grafting connector molecules is demonstrated and discussed in detail and supported by a range of experimental examples. It is shown, in agreement with contemporary theory, that the use of chemically attached graft chemicals of controlled spatial geometry and chemical functionality enables a significant increase in the strength and fracture energy of the interphase, to the point of cohesive fracture of the substrate, or that of an adjacent medium such as adhesive, elastomer, or other material. This occurs even after prolonged exposure of investigated systems to adverse environments such as hot water. POLYMERS SURFACE MODIFICATION ADHESION ADHESIVE BONDING FRACTURE ENERGY MOLECULAR BRUSHES ADHESIVES Gutowski, W.S. Li, S. Filippou, C. Hoobin, P. Petinakis, S. https://drive.google.com/file/d/1BducDTp5jazuGTp59rRuhSHQNGMKVLeD/view?usp=drivesdk Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx Loc REF1 250602s9999 xx |||||s2 |||| ||und|d 22352 22352 0 0 Loc 0 0 F1 CICY CICY RE 2025-06-25 0 B-12202 2025-06-25 14:07:05 2025-06-25 REF1